CHIRAL MONOLAYER OF SELF-ASSEMBLED DELTA-[OS(BPY)(2)L(CL)](-BIPYRIDYLL=1,2-BIS(4-PYRIDYL)ETHANE] ON A PLATINUM-ELECTRODE() [BPY EQUALS 2,2')

Authors
INOSE Y MONIWA S ARAMATA A YAMAGISHI A",KYAWNAING
Citation
Y. Inose et al., CHIRAL MONOLAYER OF SELF-ASSEMBLED DELTA-[OS(BPY)(2)L(CL)](-BIPYRIDYLL=1,2-BIS(4-PYRIDYL)ETHANE] ON A PLATINUM-ELECTRODE() [BPY EQUALS 2,2'), Chemical communications, (1), 1997, pp. 111-112
Citations number
18
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
1
Year of publication
1997
Pages
111 - 112
Database
ISI
SICI code
1359-7345(1997):1<111:CMOSD>2.0.ZU;2-2
Abstract
A chiral osmium Complex, Delta-(2,2'-bipyridyl) [1,2-bis(4-pyridyl)eth ane] chloroosmium Delta-[Os(bpy)(2)L(Cl)](+), is successfully self-ass embled at a monolayer molecular level on a clean Pt electrode in non-a queous solutions; the self-assembled Delta-[Os(bpy)(2)LCl](+) ions sho w a phenomenally repulsive interaction with each other on Pt in chiral -field formation and also in the (OsOsIII)-Os-II redox reaction, while racemic complexes interact less repulsively with each other.