PHOSPHOROTHIOATE-MERCAPTOPHOSPHONATE REARRANGEMENT - SYNTHESIS OF NEWO-MERCAPTOARYL-PHOSPHONATE AND O-MERCAPTOHETEROARYL-PHOSPHONATE AND THEIR DERIVATIVES
S. Masson et al., PHOSPHOROTHIOATE-MERCAPTOPHOSPHONATE REARRANGEMENT - SYNTHESIS OF NEWO-MERCAPTOARYL-PHOSPHONATE AND O-MERCAPTOHETEROARYL-PHOSPHONATE AND THEIR DERIVATIVES, Bulletin de la Societe chimique de France, 133(10), 1996, pp. 951-964
New o-mercaptoaryl and o-mercaptoheteroaryl phosphonates and their der
ivatives were prepared via an ortho-lithiation of O,O-diisopropyl S-ar
yl: S-(2-pyridyl), S-(2-thienyl) and S-(3-thienyl) phosphorothioates f
ollowed by a phosphonyl group S --> C migration.