PERFLUOROVINYL-METAL DERIVATIVES - A NEW ONE-POT SYNTHESIS

Authors
BANGER KK BRISDON AK GUPTA A
Citation
Kk. Banger et al., PERFLUOROVINYL-METAL DERIVATIVES - A NEW ONE-POT SYNTHESIS, Chemical communications, (1), 1997, pp. 139-140
Citations number
5
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
1
Year of publication
1997
Pages
139 - 140
Database
ISI
SICI code
1359-7345(1997):1<139:PD-ANO>2.0.ZU;2-C
Abstract
The one-pot reaction of the CFC replacement 1,1,1,2-tetrafluoroethane (CF3CFH2, HFC-134a) with 2 equiv. of butyllithium in diethyl ether at -78 degrees C followed by the addition of main-group or transition-met al halides results in good yields of the corresponding metal-perfluoro vinyl compounds of high purity.