A. Berengolts et al., DYNAMIC ORIENTATION OF DIATOMIC FRAGMENTS FORMED IN THE DECOMPOSITIONOF STATISTICAL TRIATOMIC COMPLEXES .2. CLASSICAL SIMULATION, Chemical physics, 195(1-3), 1995, pp. 283-289
The classical simulation of the dynamic rotational orientation of a di
atomic fragment formed in the decomposition of a long-lived triatomic
complex is presented. The results obtained complement our previous stu
dy of the same phenomenon within the semiclassical approach and cover
a wide range of practically interesting cases of rotational orientatio
n for a system charge-rotating linear dipole. A simple analytical form
ula is suggested for a quick estimate of the orientation for general p
ower-law adiabatic channel potentials.