FABRICATION OF HIGHLY STABLE AND LOW DEFECT DENSITY AMORPHOUS-SILICONFILMS AT LOW SUBSTRATE-TEMPERATURE BY PLASMA CHEMICAL-VAPOR-DEPOSITION ASSISTED WITH PIEZOELECTRIC VIBRATION
M. Sumiya et al., FABRICATION OF HIGHLY STABLE AND LOW DEFECT DENSITY AMORPHOUS-SILICONFILMS AT LOW SUBSTRATE-TEMPERATURE BY PLASMA CHEMICAL-VAPOR-DEPOSITION ASSISTED WITH PIEZOELECTRIC VIBRATION, JPN J A P 2, 34(1B), 1995, pp. 97-100
Plasma chemical vapor deposition (CVD) of a-Si:H films has been conduc
ted under the application of piezoelectric vibration to the substrates
with the expectation of enhancing the surface migration of the precur
sors. Defect density of the order 10(15) cm(-3) was achieved for a fil
m deposited at 120 degrees C under 2 MHz piezoelectric vibration. The
photodegradation behavior of the deposited films was measured using ir
radiation by pulsed ruby laser as well as by Xe lamp. The prolonged li
ght soaking increased the defect densities in the a-Si:H films as well
as those in the films deposited by the conventional method, i.e., wit
hout the piezoelectric vibration. However, the saturated value for the
former films remained at 3 x 10(16) cm(-3), significantly lower than
the value (similar to 10(17) cm(-3)) for the latter. The activation en
ergy for recovery from the light-induced defect of a-Si:H was higher f
or the film deposited with piezoelectric vibration than the film depos
ited without the vibration. Thus, the piezoelectric vibration apparent
ly functioned not only to reduce the defect density in as-deposited fi
lms but also to improve the stability against light soaking.