Jr. Manson, THE TRANSITION FROM QUANTUM TO CLASSICAL ATOM-SURFACE SCATTERING, Nuclear instruments & methods in physics research. Section B, Beam interactions with materials and atoms, 96(3-4), 1995, pp. 497-507
We present a fully quantum mechanical model of atom-surface scattering
which can be extended through the correspondence principle to the cla
ssical limit. Calculations for comparison with recent He atom scatteri
ng experiments on the Cu(001) surface show excellent agreement with th
e observed diffuse inelastic backgrounds. The temperature dependence o
f the scattering in the classical regime demonstrates conclusively tha
t the He atoms exchange energy with a vibrating continuum interaction
potential due to the surface electron density and not directly with a
lattice of surface atomic cores.