HIGH-ENERGY CHEMISTRY CAUSED BY FAST ION-SOLID INTERACTIONS

Citation
Mj. Vanstipdonk et Ea. Schweikert, HIGH-ENERGY CHEMISTRY CAUSED BY FAST ION-SOLID INTERACTIONS, Nuclear instruments & methods in physics research. Section B, Beam interactions with materials and atoms, 96(3-4), 1995, pp. 530-535
Citations number
29
Categorie Soggetti
Physics, Nuclear","Nuclear Sciences & Tecnology","Instument & Instrumentation
ISSN journal
0168583X
Volume
96
Issue
3-4
Year of publication
1995
Pages
530 - 535
Database
ISI
SICI code
0168-583X(1995)96:3-4<530:HCCBFI>2.0.ZU;2-U
Abstract
Plasma desorption induced by the impact of Cf-252 fission fragments wa s used to study the emission of positive cluster ions from a lanthanum nitrate, La(NO3)(3) . 6H(2)O, substrate. Two large series of peaks we re observed. One corresponded to the addition of LaO+ to a repeating b ase unit of La2O3. A less intense series contained the same base unit, with H+ attachment. Neither series contained clusters that reflect th e structure or stoichiometry of the original sample. We propose that t he cluster ions are produced by high temperature and pressure chemical reactions inside the fast ion track.