Mj. Vanstipdonk et Ea. Schweikert, HIGH-ENERGY CHEMISTRY CAUSED BY FAST ION-SOLID INTERACTIONS, Nuclear instruments & methods in physics research. Section B, Beam interactions with materials and atoms, 96(3-4), 1995, pp. 530-535
Plasma desorption induced by the impact of Cf-252 fission fragments wa
s used to study the emission of positive cluster ions from a lanthanum
nitrate, La(NO3)(3) . 6H(2)O, substrate. Two large series of peaks we
re observed. One corresponded to the addition of LaO+ to a repeating b
ase unit of La2O3. A less intense series contained the same base unit,
with H+ attachment. Neither series contained clusters that reflect th
e structure or stoichiometry of the original sample. We propose that t
he cluster ions are produced by high temperature and pressure chemical
reactions inside the fast ion track.