Dw. Mccomb et A. Howie, VALENCE LOSS SPECTRA FROM SIO2 POLYMORPHS OF DIFFERENT DENSITY, Nuclear instruments & methods in physics research. Section B, Beam interactions with materials and atoms, 96(3-4), 1995, pp. 569-574
Dielectric response functions for stishovite, coesite, cu-quartz and s
ilacalite, obtained from electron energy loss spectra are studied and
compared. The data for stishovite conforms well to simple dielectric t
heory for an insulator. However the behaviour of the other materials,
including the relative insensitivity of the plasmon peak to density, i
s less well explained either on this basis or using more elaborate mod
els based on Maxwell Garnett or Clausius-Mossotti effective medium the
ory. Possible improvements to effective medium theory are discussed.