LOW-TEMPERATURE SYNTHESIS OF METAL NANOMETER-SCALE PARTICLES IN TRIETHYLAMINE MEDIUM

Authors
KONDAKOV SE SMIRNOV VV OLENIN AY
Citation
Se. Kondakov et al., LOW-TEMPERATURE SYNTHESIS OF METAL NANOMETER-SCALE PARTICLES IN TRIETHYLAMINE MEDIUM, Bulletin des Societes chimiques belges, 104(6), 1995, pp. 369-373
Citations number
21
Categorie Soggetti
Chemistry
Journal title
Bulletin des Societes chimiques belges → ACNP
ISSN journal
00379646
Volume
104
Issue
6
Year of publication
1995
Pages
369 - 373
Database
ISI
SICI code
0037-9646(1995)104:6<369:LSOMNP>2.0.ZU;2-V
Abstract
The process of metal cluster formation has been stud led in conditions of metal vapor synthesis with tertiary amines. The samples have been investigated by IR, UV-VIS, ESR and photon correlation spectroscopy. F or the first time the nature of matrix complexes of the free metal and triethylamine have been discussed in terms of donor-acceptor properti es. It has been shown that the using of triethylamine as cryomatrix le ads to the formation of stable ultrafine (Mg, Mn, Cu, Na, Sm, Pb) meta l particles.