1,3-BIS(TRIPHENYLPHOSPHONIUM-YLIDYL)CYCLO TETRAPHOSPHANE

Authors
JOCHEM G SCHMIDPETER A KARAGHIOSOFF K NOTH H
Citation
G. Jochem et al., 1,3-BIS(TRIPHENYLPHOSPHONIUM-YLIDYL)CYCLO TETRAPHOSPHANE, Zeitschrift fur anorganische und allgemeine Chemie, 621(6), 1995, pp. 931-935
Citations number
21
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur anorganische und allgemeine Chemie
ISSN journal
00442313 → ACNP
Volume
621
Issue
6
Year of publication
1995
Pages
931 - 935
Database
ISI
SICI code
0044-2313(1995)621:6<931:1T>2.0.ZU;2-8
Abstract
The title compounds 3a, b result from the condensation of the ylidyldi chlorophosphines Ph(3)PCR-PCl2 1a, b (R = Me, 3-Tol) with phenyl bis(t rimethylsilyl)phosphine 2. Analysis of the P-31-NMR spectra and the X- ray structure investigation of 3 a demonstrate a folding of the four-m embered ring and an all-trans orientation of the substituents.