CHEMICAL-VAPOR TRANSPORT OF INTERMETALLIC SYSTEMS CHEMICAL-TRANSPORT OF CU AG-MIXED CRYSTALS/

Citation
S. Gerighausen et M. Binnewies, CHEMICAL-VAPOR TRANSPORT OF INTERMETALLIC SYSTEMS CHEMICAL-TRANSPORT OF CU AG-MIXED CRYSTALS/, Zeitschrift fur anorganische und allgemeine Chemie, 621(6), 1995, pp. 936-940
Citations number
8
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur anorganische und allgemeine Chemie
ISSN journal
00442313 → ACNP
Volume
621
Issue
6
Year of publication
1995
Pages
936 - 940
Database
ISI
SICI code
0044-2313(1995)621:6<936:CTOISC>2.0.ZU;2-Z
Abstract
By means of chemical transport reaction it is possible to prepare Cu-r ich and Ag-rich mixed crystals in the Cu/Ag system. The composition of individual deposited crystals was different. Mass-spectrometric analy sis of the gas-phase above CuI/AgI has shown the formation of CuAg2I3, g and Cu(2)AgI3,g. Thermodynamic computations explain the formation of crystals as well as the reaction conditions.