S. Gerighausen et M. Binnewies, CHEMICAL-VAPOR TRANSPORT OF INTERMETALLIC SYSTEMS CHEMICAL-TRANSPORT OF CU AG-MIXED CRYSTALS/, Zeitschrift fur anorganische und allgemeine Chemie, 621(6), 1995, pp. 936-940
Citations number
8
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur anorganische und allgemeine Chemie
By means of chemical transport reaction it is possible to prepare Cu-r
ich and Ag-rich mixed crystals in the Cu/Ag system. The composition of
individual deposited crystals was different. Mass-spectrometric analy
sis of the gas-phase above CuI/AgI has shown the formation of CuAg2I3,
g and Cu(2)AgI3,g. Thermodynamic computations explain the formation of
crystals as well as the reaction conditions.