SYNTHESIS AND CRYSTAL-STRUCTURE OF [CP(2) MOHLI(THF)](3)CENTER-DOT TOLUENE

Authors
MANDEL A MAGULL J
Citation
A. Mandel et J. Magull, SYNTHESIS AND CRYSTAL-STRUCTURE OF [CP(2) MOHLI(THF)](3)CENTER-DOT TOLUENE, Zeitschrift fur anorganische und allgemeine Chemie, 621(6), 1995, pp. 945-947
Citations number
8
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur anorganische und allgemeine Chemie
ISSN journal
00442313 → ACNP
Volume
621
Issue
6
Year of publication
1995
Pages
945 - 947
Database
ISI
SICI code
0044-2313(1995)621:6<945:SACO[M>2.0.ZU;2-T
Abstract
[Cp(2)MoHLi](4) reacts in THF/Toluene to the trimeric complex [Cp(2)Mo HLi(thf)](3) . Toluene 1. The structure of 1 was characterized by X-ra y single crystal structure analysis. Space group P6(3), Z = 2, a = 145 9.5(9) pm, c = 1182.3(8)pm. The central unit is represented by a Mo3Li 3-hexagon. Each Mo-Atom is surrounded by two Cp-Ligands. One THF-Molec ule is coordinated to each Li-atom. The Hydrogen-Ligand could not be l ocated by the single crystal structure analysis.