LOW-TEMPERATURE SPECIFIC-HEATS OF LANTHANUM AND YTTRIUM PHOSPHATE-GLASSES

The specific heats of (R(2)O(3))(x)(P2O5)(1-x) glasses containing high concentrations of La3+ and Y3+ ions have been measured between 1.5 K and 30 K. It is shown that, in addition to the usual Debye contributio n, there is an excess specific heat arising from localized vibrational states which has been discussed in terms of two distinct models. The first predicts a maximum in the temperature dependence of the excess s pecific heat associated with the crossover frequency from phonon to fr acton behaviour. The phonon-fracton density of states used to fit the excess specific heat gives rise to model parameters having the same ma gnitudes as those found previously for other glasses including samariu m phosphates. The second model, formulated on the basis of soft vibrat ions in glasses, predicts a minimum in the excess specific heat, which is also observed.