SIMPLE DESIGN FOR THE CONSTRUCTION OF COMPLEX GIBBERELLIN FRAMEWORK STEREOSELECTIVE SYNTHESIS OF A POSSIBLE KEY INTERMEDIATE TO GA(12) VIA PD2-PROMOTED CYCLOALKENYLATION REACTION()

Authors
TOYOTA M WADA T NISHIKAWA Y YANAI K FUKUMOTO K KABUTO C
Citation
M. Toyota et al., SIMPLE DESIGN FOR THE CONSTRUCTION OF COMPLEX GIBBERELLIN FRAMEWORK STEREOSELECTIVE SYNTHESIS OF A POSSIBLE KEY INTERMEDIATE TO GA(12) VIA PD2-PROMOTED CYCLOALKENYLATION REACTION(), Tetrahedron, 51(25), 1995, pp. 6927-6940
Citations number
23
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
51
Issue
25
Year of publication
1995
Pages
6927 - 6940
Database
ISI
SICI code
0040-4020(1995)51:25<6927:SDFTCO>2.0.ZU;2-X
Abstract
A successful design for the construction of C-20 gibberellin framework has been described. The key features of the synthesis are as follows: (a) Pd2+-promoted cycloalkenylation reaction (6-->15) and (b) intramo lecular Diels-Alder reaction (4-->3).