AZA-DIHYDRO[60]FULLERENE IN THE GAS-PHASE - A MASS-SPECTROMETRIC AND QUANTUMCHEMICAL STUDY

Authors
AVERDUNG J LUFTMANN H SCHLACHTER I MATTAY J
Citation
J. Averdung et al., AZA-DIHYDRO[60]FULLERENE IN THE GAS-PHASE - A MASS-SPECTROMETRIC AND QUANTUMCHEMICAL STUDY, Tetrahedron, 51(25), 1995, pp. 6977-6982
Citations number
25
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
51
Issue
25
Year of publication
1995
Pages
6977 - 6982
Database
ISI
SICI code
0040-4020(1995)51:25<6977:AITG-A>2.0.ZU;2-R
Abstract
A new approach to produce heterofullerenes is described. Starting from a fullerene with an intact cage which is activated by suitable exohed ral functionalization, the first aza-heterofullerene is generated in t he gas phase under DCl mass-spectrometric conditions. On the basis of AMl-calculations the 1,2-closed structure is proposed to be the most s table one.