HOMOGENEOUS CATALYTIC REDUCTION OF NO IN THE PRESENCE OF CO(III) COMPLEXES

Authors
DOZSA L PENZELI P
Citation
L. Dozsa et P. Penzeli, HOMOGENEOUS CATALYTIC REDUCTION OF NO IN THE PRESENCE OF CO(III) COMPLEXES, Reaction kinetics and catalysis letters, 55(1), 1995, pp. 121-126
Citations number
8
Categorie Soggetti
Chemistry Physical
Journal title
Reaction kinetics and catalysis letters → ACNP
ISSN journal
01331736
Volume
55
Issue
1
Year of publication
1995
Pages
121 - 126
Database
ISI
SICI code
0133-1736(1995)55:1<121:HCRONI>2.0.ZU;2-B
Abstract
Several Co(III) complexes have been found to be active catalysts in th e reaction of NO with n-butylamine. N-2 and N2O were identified as gas eous products of the reduction. Isotope scrambling in N-2 and N2O in t he experiments with N-15 enriched NO suggests two types of stoichiomet ric processes. The catalysis is interpreted by formation of a NO-compl ex as intermediate.