SAPO-5 AND SAPO-11 - SYNTHESIS, CHARACTERIZATION AND CAMPHENE ISOMERIZATION ACTIVITY

Authors
ELANGOVAN SP KRISHNASAMY V MURUGESAN V
Citation
Sp. Elangovan et al., SAPO-5 AND SAPO-11 - SYNTHESIS, CHARACTERIZATION AND CAMPHENE ISOMERIZATION ACTIVITY, Reaction kinetics and catalysis letters, 55(1), 1995, pp. 153-159
Citations number
14
Categorie Soggetti
Chemistry Physical
Journal title
Reaction kinetics and catalysis letters → ACNP
ISSN journal
01331736
Volume
55
Issue
1
Year of publication
1995
Pages
153 - 159
Database
ISI
SICI code
0133-1736(1995)55:1<153:SAS-SC>2.0.ZU;2-8
Abstract
SAPO-5 and SAPO-11 were synthesized using aluminium isopropoxide and t etraethyl orthosilicate as source materials for aluminium and silicon, respectively, adopting a modified procedure. The as-synthesized mater ials were characterized by XRD and chemical analysis. Acidity was foun d by temperature-programmed desorption using TGA. Unit cell parameters were calculated for both as-synthesized and calcined materials. The c atalytic activity of SAPO-5 and SAPO-11 in camphene isomerization was studied and selective formation of tricyclene was achieved.