PREPARATION OF ALPHA-DIENYL AND BETA-DIENYL GLYCOSIDES USED AS DIENESIN AQUEOUS DIELS-ALDER REACTIONS - INFLUENCE OF THE CARBOHYDRATE MOIETY ON THE THERMODYNAMICS OF THE REACTION

Authors
LUBINEAU A BIENAYME H QUENEAU Y
Citation
A. Lubineau et al., PREPARATION OF ALPHA-DIENYL AND BETA-DIENYL GLYCOSIDES USED AS DIENESIN AQUEOUS DIELS-ALDER REACTIONS - INFLUENCE OF THE CARBOHYDRATE MOIETY ON THE THERMODYNAMICS OF THE REACTION, Carbohydrate research, 270(2), 1995, pp. 163-179
Citations number
31
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Carbohydrate research → ACNP
ISSN journal
00086215
Volume
270
Issue
2
Year of publication
1995
Pages
163 - 179
Database
ISI
SICI code
0008-6215(1995)270:2<163:POAABG>2.0.ZU;2-3
Abstract
A series of 1,3-butadienyl glycosides (mono- and di-saccharides) have been prepared and the kinetics of their Diels-Alder reaction with bute n-2-one in water have been studied. The activation parameters for thes e aqueous cycloadditions provide clues for the hydration structure of such glyco-organic compounds.