COBALT(II) AND IRON(III) COMPLEXES WITH 2-(ACETOACETOXY)ETHYLMETHACRYLATE - POTENTIAL PRECURSORS OF HYBRID CATALYSTS

Authors
MASTRORILLI P NOBILE CF MARCHESE G
Citation
P. Mastrorilli et al., COBALT(II) AND IRON(III) COMPLEXES WITH 2-(ACETOACETOXY)ETHYLMETHACRYLATE - POTENTIAL PRECURSORS OF HYBRID CATALYSTS, Inorganica Chimica Acta, 233(1-2), 1995, pp. 65-69
Citations number
33
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganica Chimica Acta → ACNP
ISSN journal
00201693
Volume
233
Issue
1-2
Year of publication
1995
Pages
65 - 69
Database
ISI
SICI code
0020-1693(1995)233:1-2<65:CAICW2>2.0.ZU;2-7
Abstract
The synthesis and characterization of homo- and heteroleptic beta-keto esterate complexes of cobalt(II) and iron(III) by reaction of their ni trates and/or acetates with 2-(acetoacetoxy)ethylmethacrylate (HAAEMA) is described. The obtained complexes bear non-coordinated carbon-carb on double bonds and are therefore potential precursors of hybrid catal ysts. The homoleptic Co(AAEMA)(2) and Fe(AAEMA)(3) complexes are obtai ned when Co(NO3)(2) or Fe(NO3)(3) reacts in alkaline medium with HAAEM A whereas the heteroleptic Co(AAEMA)(AcO) complex is formed starting f rom Co(AcO)(2) and HAAEMA.