X-RAY STRUCTURE OF ORO-[BIS(2-DIPHENYLPHOSPHINOETHYL)PHENYLPHOSPHINE](DIMETHYL SULFOXIDE)RUTHENIUM(II)

Authors
DELGADO G RIVERA AV SUAREZ T FONTAL B
Citation
G. Delgado et al., X-RAY STRUCTURE OF ORO-[BIS(2-DIPHENYLPHOSPHINOETHYL)PHENYLPHOSPHINE](DIMETHYL SULFOXIDE)RUTHENIUM(II), Inorganica Chimica Acta, 233(1-2), 1995, pp. 145-149
Citations number
39
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganica Chimica Acta → ACNP
ISSN journal
00201693
Volume
233
Issue
1-2
Year of publication
1995
Pages
145 - 149
Database
ISI
SICI code
0020-1693(1995)233:1-2<145:XSOO>2.0.ZU;2-V
Abstract
The complex RuCl2(TRIPHOS)(DMSO). C6H5CH3 is monoclinic, P2(1)/c, with a=21.070(5), b=11.968(3), c=16.892(4) Angstrom, beta=107.7(2)degrees, V=4057.2 Angstrom(3), Z=4. The crystal structure consists of discrete molecules of the complex and solvent held together by normal van der Waals forces. The ruthenium atom is hexacoordinated. Dimethyl sulfoxid e binds through the sulfur atom and the TRIPHOS ligand occupies three coordination sites.