The water content of a sludge is generally considered to be constitute
d by two fractions: free water and bound water. This classification do
es not, however, characterize the binding energy of water to the solid
phase. By using the dilatometric technique, the bound water content o
f sludge was measured as a function of the mechanical dewatering strai
n applied to the sludge. Thus, it was possible to separate water into
different categories (free water, bound water removable by moderate me
chanical strain, bound water removable by maximal mechanical strain, b
ound water not removable mechanically), depending on its behavior duri
ng mechanical dewatering.