H. Fukaya et al., NEW FIRE SUPPRESSION MECHANISM OF PERFLUOROALKYLAMINES, Journal of the Chemical Society, Chemical Communications, (12), 1995, pp. 1207-1208
Ab initio molecular orbital calculations on the reactions of the trifl
uoromethyl radical,which can be easily released from perfluoroalkylami
ne by dissociation of C-N bonds with hydroxyl or hydrogen radicals rev
ealed the fire extinguishing mechanism of non-bromine-containing halon
replacements such as perfluoroalkylamines.