PROP-2-YNYL ALCOHOL ASA PRECURSOR TO THE ETA(1)-ETHENYL LIGAND

Authors
OCONNOR JM HIIBNER K
Citation
Jm. Oconnor et K. Hiibner, PROP-2-YNYL ALCOHOL ASA PRECURSOR TO THE ETA(1)-ETHENYL LIGAND, Journal of the Chemical Society, Chemical Communications, (12), 1995, pp. 1209-1210
Citations number
23
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
12
Year of publication
1995
Pages
1209 - 1210
Database
ISI
SICI code
0022-4936(1995):12<1209:PAAPTT>2.0.ZU;2-N
Abstract
In the presence of water the unsaturated iridium (III) metallacyclopen tadiene halide complex Ir(CR=CRCR=CR)(PPh(3))(2)Cl (1, R = CO(2)Me) un dergoes reaction with prop-2-ynyl alcohol, or methyl prop-2-ynyl ether at room temperature to give the eta(1)-ethenyl complex Ir(CR=CRCR=CR) (PPh(3))2(CO)(eta(1)-CH=CH2) (3, R = CO(2)Me) in quantitative yield.