LINEAR FACE-SHARING TRIOCTAHEDRAL [MO3I12](3-) BY SPONTANEOUS THF LOSS FROM[MOI4(THF)(2)](-) - STRUCTURE, BONDING AND MAGNETIC-PROPERTIES

Authors
FETTINGER JC MATTAMANA SP OCONNOR CJ POLI R SALEM G
Citation
Jc. Fettinger et al., LINEAR FACE-SHARING TRIOCTAHEDRAL [MO3I12](3-) BY SPONTANEOUS THF LOSS FROM[MOI4(THF)(2)](-) - STRUCTURE, BONDING AND MAGNETIC-PROPERTIES, Journal of the Chemical Society, Chemical Communications, (12), 1995, pp. 1265-1266
Citations number
16
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
12
Year of publication
1995
Pages
1265 - 1266
Database
ISI
SICI code
0022-4936(1995):12<1265:LFT[BS>2.0.ZU;2-1
Abstract
Complexes [Mo(3)X(12)](3-) (X = I, Br) assemble by spontaneous thf los s in noncoordinating solvents from [MoX(4)(thf)(2)](-) and exhibit a l inear face-shared trioctahedral structure with, at the same time, delo calized metal-metal bonding and local moment antiferromagnetic exchang e interactions.