USE OF TRIMETHYLAMINE N-OXIDE IN THE CONTROLLED AIR-OXIDATION OF METAL-CARBONYL-COMPLEXES - SYNTHESIS AND CRYSTAL-STRUCTURE OF A NOVEL ORGANOMETALLIC OXO COMPLEX OF DIMOLYBDENUM

Authors
STICHBURY JC MAYS MJ RAITHBY PR RENNIE MA FULLALOVE MR
Citation
Jc. Stichbury et al., USE OF TRIMETHYLAMINE N-OXIDE IN THE CONTROLLED AIR-OXIDATION OF METAL-CARBONYL-COMPLEXES - SYNTHESIS AND CRYSTAL-STRUCTURE OF A NOVEL ORGANOMETALLIC OXO COMPLEX OF DIMOLYBDENUM, Journal of the Chemical Society, Chemical Communications, (12), 1995, pp. 1269-1270
Citations number
16
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
12
Year of publication
1995
Pages
1269 - 1270
Database
ISI
SICI code
0022-4936(1995):12<1269:UOTNIT>2.0.ZU;2-U
Abstract
The air oxidation of [Mo-2(CO)(4)(mu-RCCR')(eta(5)-C5H5)(2)] in the pr esence of trimethylamine N-oxide affords the novel organometallic comp lexes [Mo2O2(mu-O)(mu-RCCR')(eta(5)-C5H5)(2)] [R = R' = CO(2)Me or Ph; R = CO(2)Me, R' = H; R = Ph, R' = H) which are characterised spectros copically; the structure of 2O2(mu-O)(mu-MeO(2)C-C-2-CO(2)Me)(eta(5)-C 5H5)(2)] 1 is determined by X-ray crystallography.