CATALYTIC TRANSFORMATIONS OF 3-CARENE OXIDE OVER ALUMINA-RARE EARTH OXIDE CATALYSTS

Authors
JAYASREE J NARAYANAN CS
Citation
J. Jayasree et Cs. Narayanan, CATALYTIC TRANSFORMATIONS OF 3-CARENE OXIDE OVER ALUMINA-RARE EARTH OXIDE CATALYSTS, Indian journal of chemistry. Sect. B: organic chemistry, including medical chemistry, 34(7), 1995, pp. 577-580
Citations number
20
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Indian journal of chemistry. Sect. B: organic chemistry, including medical chemistry → ACNP
ISSN journal
03764699
Volume
34
Issue
7
Year of publication
1995
Pages
577 - 580
Database
ISI
SICI code
0376-4699(1995)34:7<577:CTO3OO>2.0.ZU;2-E
Abstract
Isomerization of 3-carene oxide over binary oxide catalysts like Al2O3 -Y2O3, Al2O3-Sm2O3, Al2O3-Eu2O3, Al2O3-Pr6O11 and Al2O3-Nd2O3 at 80 de grees C and 110 degrees C has been studied. ,6-Trimethyl-bicyclo[3.1.0 ]hexane-3-carboxaldehyde and caranone are the major products formed at 80 degrees C. Rise in reaction temperature results in an increase in epoxide transformation and an irregular variation in the yield of prod ucts.