Microstructural observations and measurements of the retained austenit
e content, hardness, austenite C content, and unreacted austenite cont
ent are reported during austempering at 400, 375, 320, and 285 degrees
C after austenitising at 920 degrees C for a ductile iron containing
3.52%C, 2.64%Si, 0.67%Mn, 0.007%P, 0.013%S, 0.25%Mo, 0.25%Cu, and 0.04
%Mg. The segregation of solute during solidification to the intercellu
lar areas is shown to result in the stage I reactions in the eutectic
cell and intercellular areas being separated in austempering time. Evi
dence is provided of the occurrence of the stage II reaction before th
e completion of the stage reaction. The consequence of this sequence o
f changes is that she processing window as defined for unalloyed irons
and known to correspond to optimum mechanical properties is closed fo
r all austempering temperatures.