A. Hesse et al., ZERO-AOX SHRINKPROOFING TREATMENT FOR WOOL TOP AND FABRIC .2. COLLAGEN RESIN APPLICATION, Textile research journal, 65(7), 1995, pp. 371-378
The halogen-free shrinkproofing resin presented in this work is based
on the natural protein collagen and a crosslinking agent, which provid
es a covalent linkage between the wool and the resin (collagen). Glyci
dylacrylate and the trifunctional epoxide Araldit PT 810 are applied a
s crosslinkers. Almost complete shrink resistance of wool fabric and t
op is achieved using the collagen/Araldit resin with plasma pretreated
material. In combination with the oxidative plasma treatment describe
d in Part I, the additive collagen treatment appears to be an effectiv
e substitute for the chlorine/Hercosett process.