Jk. Burdett, TOPOLOGICAL ASPECTS OF CHEMICAL BONDING AND STRUCTURE EXPLORED THROUGH THE METHOD OF MOMENTS, Journal of molecular structure. Theochem, 336(2-3), 1995, pp. 115-136
Some recent developments in the application of the Moments Method to s
tructural problems are described. They include discussion of the origi
n of Pauling's second rule, the heats of mixing of some transition met
al oxides, surface problems, insights into the complexity of solids an
d ways to capture the electronic aspects of disorder. Lee's conceptual
framework for understanding the structures of the elements and alloys
and the electronic underpinnings of the Hume-Rothery rules are review
ed.