Fourier-transform (FT) near-infrared (NIR) spectroscopy has proved to
be a powerful technique in investigating structure and thermodynamic p
roperties of long-chain fatty acids and alcohols. In order to extract
useful information from the NIR spectra, bands due to the second as we
ll as first overtones of OH-stretching modes of the monomeric forms we
re employed. It has been also found that two-dimensional (2D) NIR corr
elation spectroscopy can accentuate useful information often obscured
in the complicated NIR spectral data set.