REACTION OF MAGNESIUM WITH BENZYL HALIDES IN AN OPTICALLY-ACTIVE SOLVENT

Authors
EGOROV AM ANISIMOV AV
Citation
Am. Egorov et Av. Anisimov, REACTION OF MAGNESIUM WITH BENZYL HALIDES IN AN OPTICALLY-ACTIVE SOLVENT, Journal of organometallic chemistry, 495(1-2), 1995, pp. 131-134
Citations number
20
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
495
Issue
1-2
Year of publication
1995
Pages
131 - 134
Database
ISI
SICI code
0022-328X(1995)495:1-2<131:ROMWBH>2.0.ZU;2-H
Abstract
Grignard reagent formation from benzyl halides with an asymmetric cent re in the presence of an optically active solvent proceeds on the magn esium surface within a solvent cage by one-electron transfer mechanism .