Pa. Yeats et al., CADMIUM, COPPER AND NICKEL DISTRIBUTIONS AT 4 STATIONS IN THE EASTERNCENTRAL AND SOUTH-ATLANTIC, Marine chemistry, 49(4), 1995, pp. 283-293
Distributions of cadmium, copper and nickel at four stations in the ea
stern part of the Atlantic Ocean from 30 degrees S to 34 degrees N are
described based on analytical results from three laboratories. The Cd
and Ni profiles show nutrient-like distributions with concentrations
in the deep waters increasing from north to south. Copper profiles all
show gradual increases from surface to bottom with the highest concen
trations occurring near bottom on the most northerly station. Variatio
ns in the deep-water Cd and Ni concentrations can be understood in ter
ms of mixing of southern source waters with high concentrations with l
ower concentration northern source waters. The deep-water Cu distribut
ions indicate a significant near-bottom source to the northern end of
the section. Cadmium vs. phosphate relationships show features that re
sult from both regeneration and mixing. Higher Cd:PO4 ratios are seen
in the southern source waters than in the northern waters, thus discou
nting the suggestion that the inflection in the global Cd:PO4 relation
ship at PO4 approximate to 1.3 mu M originates in the southern ocean.
Differential regeneration of Cd and PO4 is seen through the equatorial
oxygen minimum.