Ajm. Penela et G. Barragan, SILICIFICATION OF CARBONATE CLASTS IN A MARINE-ENVIRONMENT (UPPER MIOCENE, VERA BASIN, SE SPAIN), Sedimentary geology, 97(1-2), 1995, pp. 21-32
Upper Miocene marine sediments in the Vera Basin (SE Spain) contain ab
undant silicified marble pebbles and bivalves. The silicification of t
hese marble pebbles and bivalves represents one of the stages of their
sedimentary history, associated with small fluctuations in relative s
ea level. During the late Tortonian alluvial fan deposits containing t
he marble pebbles were invaded by the sea, which caused reworking of t
he pebbles and the establishment of a marine biota in the environment.
After shallow burial numerous marble pebbles and bivalve remains were
silicified. Both types of clasts were partially replaced by opal-CT o
r quartz from opaline silica derived from dissolution of skeletal debr
is. The silicified zones (rinds) now consist of quartzine or quartz. S
ilicification of the clasts must have taken place under shallow burial
conditions during early diagenesis, while pyrite formed in favourable
anoxic sites. Iron oxides also precipitated during early diagenesis,
but after silicification. Finally, part of the deposits containing the
silicified clasts were transported by gravitational mass flows and re
deposited in deeper areas of the basin. If the hypothesis proposed for
the diagenetic process is correct, it indicates that the uncommon sil
icification of carbonate clasts does not only occur in continental env
ironments, in which it has previously been described.