GENERATION AND REACTION OF BENZYLAMMONIUM N-METHYLIDES WITH N-CYANOMETHYL OR N-(ETHOXYCARBONYLALKYL) GROUPS

Authors
ZHANG C MAEDA Y SHIRAI N SATO Y
Citation
C. Zhang et al., GENERATION AND REACTION OF BENZYLAMMONIUM N-METHYLIDES WITH N-CYANOMETHYL OR N-(ETHOXYCARBONYLALKYL) GROUPS, Journal of the Chemical Society. Perkin transactions. I, (1), 1997, pp. 25-28
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Perkin transactions. I → ACNP
ISSN journal
0300922X
Issue
1
Year of publication
1997
Pages
25 - 28
Database
ISI
SICI code
0300-922X(1997):1<25:GAROBN>2.0.ZU;2-T
Abstract
N-Cyanomethyl-, N-ethoxycarbonylmethyl- and N-(3-ethoxycarbonylpropyl) -N-methylbenzylammonium N-methylides 6a,b and 22 have been generated b y fluoride ion-induced desilylation of the corresponding N-(trimethyls ilylmethyl)benzylammonium salts 5a,b and 21, Sommelet-Hauser 7, 23 and Stevens 8, 24 rearrangement products were obtained from 6a add 22, bu t not from 6b.