A new application of silica aerogels is presented, using them, for the
first time, as a mould material for the casting of metals. Aluminium
alloy melts were cast into forms machined from thick silica aerogel pl
ates. The excellent thermal insulation properties of aerogels lead to
a nearly one-dimensional cooling and solidification process. This is r
eflected by the microstructure of the solidified samples. Owing to the
transparency of the aerogels, it is also possible to study the coolin
g process with the help of optical measurements and video techniques.
Using an infrared camera, the velocity of the solidification process a
nd the temperature gradient ahead of the solid-liquid interface were o
btained from video signals. These can be directly correlated with the
microstructure. The successful results of these casting experiments ha
ve initiated a more detailed study of the potential offered by aerogel
s for researching solidification processes. One example is a new type
of Bridgeman furnace using aerogels as a crucible material and a speci
al feedback loop controlling the solidification processes without mova
ble samples or heaters like in a classical Bridgeman configuration. Th
e concept of such a furnace is presented and first experimental result
s are shown.