A home made nanosecond pulse radiolysis apparatus was built at Laborat
ory of Radiation Chemistry, Academia Sinica in October 1990. The monit
oring equipment is a kinetic spectrophotometer. The measurement of opt
ical density as a function of time, absorption spectrum of transient s
pecies and kinetic parameters can be obtained simultaneously. A synchr
onization system used to harmonize the operation of Linac and monitori
ng system is the key to control the pulse radiolysis apparatus. Some i
mportant novel advances including direct confirmation and development
of our previous proposal of ''mechanism of charge transfer protection
and sensitization'' have been achieved based on a series of pulse radi
olysis studies.