DIELECTRIC-PROPERTIES AND DYNAMIC SIMULATION OF WATER BOUND TO TITANIA SILICA SURFACES

Water adsorbed on titania/silica (TS) surfaces has been studied by die lectric spectroscopy (DS) in the 3-10 MHz frequency range at T = 120-3 00 K, thermally stimulated depolarization (TSD) at the same temperatur es, H-1 NMR, and quantum chemical methods. The TSD spectra of TS have only one relaxation maximum after sample heating at 400 K. The activat ion energies of depolarization (TSD) and polarization (DS) decrease at TiO2 content increasing in TS. According to the TSD, DS, and H-1 NMR data, water adsorbed on the TS surfaces essentially in the interface-r egion forms more weakly bound clusters than on the silica surfaces. Si mulation of vibrational-rotational relaxation of the water molecules a ttached to the TS surfaces shows that the activation energy of rotatio n is a maximum for the molecules having donor-acceptor bonds, Me<--OH2 (Me = Si, Ti), in the complexes HO-Me<--OH2 + mH(2)O and it is minimu m for one water molecule linked to the Ti-O(H)-Si bridge through a hyd rogen bond.