We present high-dispersion spectra of 21 planetary nebulae in the regi
on of the Na I D lines at lambda lambda 5889, 5895. These reasonance l
ines, long used to study neutral interstellar clouds, act as tracers o
f cool, neutral material associated with the ionized nebulae. Over hal
f the observed objects show nebular components in the Na D lines, eith
er in absorption or emission, or both; some of these were not previous
ly suspected to contain neutral material. For objects in which well-re
solved absorption components are seen in the Na I lines, we estimate c
olumn densities using the doublet-ratio method, finding N(Na I) approx
imate to 10(11-13) cm(-2). For five objects previously detected at 21
cm, we estimate the ratios N(Na I)IN(H I). The values for the planetar
y nebulae are somewhat higher than for typical interstellar clouds, in
dicating that, integrated through the absorbing column, a larger fract
ion of the sodium is neutral. The layers where the Na I lines are form
ed generally appear to be expanding at similar velocities as the ioniz
ed gas, a result previously found for H I. A couple of objects show bl
ue wings in the nebular Na absorptions, possibly indicating accelerati
on, nonspherical ejection, or the presence of clumps of low-ionization
, fast-moving material. Our results imply that the outer portions of m
any planetary nebulae are neutral. Therefore, the nebulae are radiatio
n-bounded rather than mass-bounded, and the total masses are larger th
an the ionized masses. Resonance lines such as the Na I lines offer a
means of detecting circumnebular material whether or not molecules are
present, and of investigating properties of the neutral envelopes suc
h as ionization balance, column densities, and kinematics.