AN ORGANOMETAL HYDROXIDE ROUTE TO ([(C8H12)RH](2)[TI(OPRN)(6)])

Authors
DAY VW EBERSPACHER TA HAO JL KLEMPERER WG ZHONG BX
Citation
Vw. Day et al., AN ORGANOMETAL HYDROXIDE ROUTE TO ([(C8H12)RH](2)[TI(OPRN)(6)]), Inorganic chemistry, 34(13), 1995, pp. 3549-3552
Citations number
21
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
34
Issue
13
Year of publication
1995
Pages
3549 - 3552
Database
ISI
SICI code
0020-1669(1995)34:13<3549:AOHRT(>2.0.ZU;2-5
Abstract
The 1,5-cyclooctadiene complex {[(C8H12)Rh(OH)](2)} reacts with 1 equi v of Ti(OPrn)(4) to form {[(C8H12)Rh(OPrn)]2}. When excess Ti(OPrn)(4) is employed, the Ti(OPrn)(4) adduct {[(C8H12)Rh](2)[Ti(OPrn)(6)]} is formed. The title complex is unstable in solution,dissociating into ([ (C8H12)Rh(OPrn)](2)) and Ti(OPrn)(4).