L. Berdie et al., COMBINED FATTY-ACIDS AND AMINO-ACIDS IN THE DISSOLVED PLUS COLLOIDAL AND PARTICULATE FRACTIONS OF THE WATERS FROM A DYSTROPHIC LAKE, Organic geochemistry, 23(4), 1995, pp. 343-353
The combined amino acids and fatty acids in the dissolved + colloidal
and particulate phases of the waters from a dystrophic lake have been
studied. The former encompass 0.9-1.5% of the dissolved organic carbon
(DOC) and about 10% of the particulate organic carbon (POC). The latt
er are minor compounds representing 0.023-0.067% and about 0.3% of DOC
and POC, respectively. The high phase distribution coefficients of al
l individual components are indicative of the fatty acid and amino aci
d association with organic materials that are predominant in the suspe
nded particles. Furthermore, their similar coefficients point to a rat
her uniform phase distribution pattern which is characteristic of part
itioning between the particulate and the colloidal fraction. Despite t
his general uniformity, two major distinct features have been observed
when comparing the composition of the two phases. These concern the d
ominance of glycine in the dissolved + colloidal fraction and the high
proportion of unsaturated fatty acids in the particulate matter. The
differences correspond with the predominance of algal and terrestrial
inputs in the particulate fraction and with the selective enrichment o
f microbial components in the dissolved + colloidal phase. The higher
proportion of microbial fatty acids in this fraction appears to be a c
haracteristic feature of this dystrophic lake when compared with the p
hase-dependent fatty acid distributions of riverine and marine waters
previously studied.