P. Karhunen et al., THE FORMATION OF DIBENZODIOXOCIN STRUCTURES BY OXIDATIVE COUPLING - AMODEL REACTION FOR LIGNIN BIOSYNTHESIS, Tetrahedron letters, 36(25), 1995, pp. 4501-4504
Oxidation of o,o'-dihydroxybiphenyl compounds together with coniferyl
alcohol yields substituted 6,7-dihydro-dibenzo-(e,g)(1,4)-dioxocins, t
hat represent a novel type of linkage in softwood lignins. The mechani
sm of formation of the 8-membered ring involves intramolecular nucleop
hilic addition to an intermediate quinone methide structure.