SYNTHESIS OF XY-1,4-PHENYLENE-CARBONYL-1,3-PHENYLENE-CARBONYL)S (M-PEKK) BY PRECIPITATION POLYCONDENSATION

Authors
ZOLOTUKHIN MG RUEDA DR CALLEJA FJB BRUIX M GILEVA NG
Citation
Mg. Zolotukhin et al., SYNTHESIS OF XY-1,4-PHENYLENE-CARBONYL-1,3-PHENYLENE-CARBONYL)S (M-PEKK) BY PRECIPITATION POLYCONDENSATION, Pure and applied chemistry, A32, 1995, pp. 897-905
Citations number
7
Categorie Soggetti
Polymer Sciences
Journal title
Pure and applied chemistry → ACNP
ISSN journal
00334545
Volume
A32
Year of publication
1995
Supplement
5-6
Pages
897 - 905
Database
ISI
SICI code
0033-4545(1995)A32:<897:SOX(>2.0.ZU;2-D
Abstract
High molecular weight m-substituted poly(ether ketone-ketone) has been synthesized by electrophilic precipitation polycondensation via two d ifferent ways: reaction of isophthaloyl chloride with diphenyl ether a nd reaction of isophthaloyl chloride with 1,3-bis(4-phenoxybenzoyl)ben zene. The second way of synthesis was found to give structurally more perfect polymers with higher molecular weights. In both cases polycond ensation proceeded with precipitation of the polymers formed as unifor m particles. The influence of reaction conditions has been studied. Mo nomer concentration and monomer stoichiometric ratio were shown to aff ect the polymer properties.