MILLIMETER-WAVE ELECTRONIC-SPECTRUM OF THE D-2(+) ION

Citation
A. Carrington et al., MILLIMETER-WAVE ELECTRONIC-SPECTRUM OF THE D-2(+) ION, Journal of the Chemical Society. Faraday transactions, 91(13), 1995, pp. 1887-1889
Citations number
12
Categorie Soggetti
Chemistry Physical","Physics, Atomic, Molecular & Chemical
ISSN journal
09565000
Volume
91
Issue
13
Year of publication
1995
Pages
1887 - 1889
Database
ISI
SICI code
0956-5000(1995)91:13<1887:MEOTDI>2.0.ZU;2-V
Abstract
We have extended our earlier microwave and IR measurements of the 2p s igma(u)-1s sigma(g) electronic spectrum of D-2(+) into the millimetre- wave region of the spectrum, and report the measurement of a further e ight vibration-rotation components. The measured transition frequencie s and the nuclear hyperfine splittings are very close to those predict ed by the best ab initio calculations.