S. Lakshmi et al., STUDY ON TIO2-MEDIATED PHOTOCATALYTIC DEGRADATION OF METHYLENE-BLUE, Journal of photochemistry and photobiology. A, Chemistry, 88(2-3), 1995, pp. 163-167
The degradation (oxidation) of methylene blue assisted by TiO2 photoca
talysis (with an irradiation wavelength of 365 nm) was investigated in
aqueous suspension. The rate constants for this heterogeneous photoca
talysis were evaluated as a function of the concentration of the dye,
the amount of TiO2 and the pH. The reaction is found to conform to a L
angmuir adsorption isotherm and the rate vs. pH profile exhibits a lin
ear increase with pH in acidic solutions with a maximum at around pH 6
.9.