L)CYCLOHEXYL]-ETA(5)-CYCLOPENTADIENYL)TITANIUM(IV)

Authors
TIAN J HU NH SHEN Q HUANG BT
Citation
J. Tian et al., L)CYCLOHEXYL]-ETA(5)-CYCLOPENTADIENYL)TITANIUM(IV), Acta crystallographica. Section C, Crystal structure communications, 51, 1995, pp. 1065-1067
Citations number
13
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
51
Year of publication
1995
Part
6
Pages
1065 - 1067
Database
ISI
SICI code
0108-2701(1995)51:<1065:L>2.0.ZU;2-2
Abstract
The title molecule, [TiCl2(C5H5)(C18H21O)], has a pseudotetrahedral be nt metallocene structure in which the cyclopentadienyl ring is symmetr ically bonded to Ti [range of Ti-C distances 2.36(1)-2.41(1)Angstrom], but the substituted cyclopentadienyl ring adopts asymmetrical bonding [Ti-C 2.33(1)-2.48(1)Angstrom] due to the interaction of the large su bstituent with the Cl(2) atom. The angle C(11)-C(1)-C(21) is 111.1(8)d egrees with the large substituent occupying a cis position with respec t to the substituted ring.