L-N-3)PYRIDINE-N](METHANOL)(METHANOLATO)NICKEL(II)

Authors
JIAN PM WANG SX SUO JS WANG LF WU QG
Citation
Pm. Jian et al., L-N-3)PYRIDINE-N](METHANOL)(METHANOLATO)NICKEL(II), Acta crystallographica. Section C, Crystal structure communications, 51, 1995, pp. 1071-1073
Citations number
6
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
51
Year of publication
1995
Part
6
Pages
1071 - 1073
Database
ISI
SICI code
0108-2701(1995)51:<1071:L>2.0.ZU;2-D
Abstract
The Ni-II atom in the title compound, [Ni(N-3)(CH3O)(CH4O)(C19H13N5)], is octahedrally coordinated by three N atoms from the tridentate 2,6- bis(2-benzimidazolyl)pyridine ligand, one N atom from the azide anion and two O atoms from methanol molecules. The four N atoms occupy equat orial positions of the octahedron, with Ni-N bond distances ranging fr om 2.O28(4) to 2.114(4) Angstrom. The methanol O atoms occupy axial po sitions with Ni-O bond distances of 2.074(3) and 2.151(3) Angstrom.