A CHELATE-STABILIZED MOLYBDENUMIMIDO-ALKYLIDENE COMPLEX, [TPMO(CHC(ME)(2)PH)(NAR)(OTF)]

Authors
VAUGHAN WM BONELLA JM ABBOUD KA
Citation
Wm. Vaughan et al., A CHELATE-STABILIZED MOLYBDENUMIMIDO-ALKYLIDENE COMPLEX, [TPMO(CHC(ME)(2)PH)(NAR)(OTF)], Acta crystallographica. Section C, Crystal structure communications, 51, 1995, pp. 1075-1078
Citations number
12
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
51
Year of publication
1995
Part
6
Pages
1075 - 1078
Database
ISI
SICI code
0108-2701(1995)51:<1075:ACMC[>2.0.ZU;2-I
Abstract
The title compound, (2,6-diisopropylphenylimido) [hydrotris(1- yrazoly l-N-3)borato](2-methyl-2-phenylpropylidene) (trifluoromethanesuifonato ) molybdenum(VI), [Mo(CF3O3S)(C10H12)(C12H17N)(C9H10BN6)], has been sy nthesized and its crystal structure determined. The geometry around th e Mo atom, tridentate tris(pyrazolyl)borate ligand, distorted octahedr on. There appears cant interaction between the ligands and the transit ion metal center. Principal distances include Mo-N(imido) 1.753(8), Mo -C(propylidene) 1.949(10), Mo-O(trifluoromethanesulfonate) 2.121(7) an d Mo-N(pyrazolyl) 2.167(8)-2.311(9)Angstrom.