HLOROBIS(7-THIABICYCLO[2.2.1]HEPTANE)PALLADIUM(II) AND HLOROBIS(7-THIA-BICYCLO[2.2.1]HEPTANE)PLATINUM(II)

Authors
PARVEZ M PRIMAK A CLARK PD
Citation
M. Parvez et al., HLOROBIS(7-THIABICYCLO[2.2.1]HEPTANE)PALLADIUM(II) AND HLOROBIS(7-THIA-BICYCLO[2.2.1]HEPTANE)PLATINUM(II), Acta crystallographica. Section C, Crystal structure communications, 51, 1995, pp. 1099-1102
Citations number
19
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
51
Year of publication
1995
Part
6
Pages
1099 - 1102
Database
ISI
SICI code
0108-2701(1995)51:<1099:HAH>2.0.ZU;2-C
Abstract
The asymmetric unit of the title Pd complex, [PdCl2(C6H10S)(2)], consi sts of two independent half molecules lying on inversion centres. The Pd atoms have square-planar coordination with Pd-S distances of 2.300( 2) and 2.313(2) Angstrom, Pd-Cl distances of 2.300(2) and 2.307(2) Ang strom, and S-Pd-Cl angles of 88.21(8) and 90.12(8)degrees. The Pt comp lex, [PtCl2(C6H10S)(2)], has the Pt atom lying on an inversion centre, also has square-planar coordination, and has a Pt-S distance of 2.286 (2), a Pt-Cl distance of 2.300(2) Angstrom and a S-Pt-Cl angle of 89.2 5(8)degrees.