(ALLYL)PALLADIUM(II) COMPLEXES WITH CHIRAL LIGANDS .1. (ALLYL)PALLADIUM(II) COMPLEXES WITH METHYLENEBIS(OXAZOLINE) LIGANDS

Authors
ZEHNDER M NEUBURGER M VONMATT P PFALTZ A
Citation
M. Zehnder et al., (ALLYL)PALLADIUM(II) COMPLEXES WITH CHIRAL LIGANDS .1. (ALLYL)PALLADIUM(II) COMPLEXES WITH METHYLENEBIS(OXAZOLINE) LIGANDS, Acta crystallographica. Section C, Crystal structure communications, 51, 1995, pp. 1109-1112
Citations number
9
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
51
Year of publication
1995
Part
6
Pages
1109 - 1112
Database
ISI
SICI code
0108-2701(1995)51:<1109:(CWCL.>2.0.ZU;2-5
Abstract
The structures of two (allyl)palladium(II) bis(oxazoline) complexes co ntaining methylethylidene)-bis(4-benzyl-4,5-dihydrooxazole) as a chira l ligand are reported; ene)bis(4-benzyl-4,5-dihydrooxazole)]palladium( II) hexafluorophosphate, [Pd(C23H26N2O2)(C3H5)]PF6, and [(R,R)-2,2'-(1 -methylethylidene)bis(4-benzyl-4, ole)][eta(3)-(1,3-diphenylallyl)]pal ladium(II) hexafluorophosphate, [Pd(C23H26N2O2)(C15H13)]PF6. Complexes of this type are of interest as enantioselective catalysts for allyli c substitution reactions. The structural data suggest a possible mecha nism for the observed enantioselectivity of these catalysts.