2-NITROPHENYL PHENOXYFORMATE, C13H9NO5

Authors
BRYANT GL KING JA
Citation
Gl. Bryant et Ja. King, 2-NITROPHENYL PHENOXYFORMATE, C13H9NO5, Acta crystallographica. Section C, Crystal structure communications, 51, 1995, pp. 1141-1143
Citations number
4
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
51
Year of publication
1995
Part
6
Pages
1141 - 1143
Database
ISI
SICI code
0108-2701(1995)51:<1141:2PC>2.0.ZU;2-9
Abstract
The title mononitrodiphenyl carbonate consitutes the simplest congener in the arylnitrocarbonate family. The structure contains two independ ent molecules. The two O-C (ester) bond lengths average 1.340 (7) (phe nyl) and 1.354(6) Angstrom, (nitrophenyl). The average C=O (carbonyl) bond length is 1.180 (7) Angstrom. In both molecules there is a close intramolecular interaction between an O atom of the nitro group and th e carbonyl C atom. The configuration and the average C ... O distance [2.672 (7) Angstrom] are similar to those observed in other nitropheny l carbonate structures.